Grayling are in good form in September. Most of the grayling in streams and rivers are within 2 to 3 hours NW from Edmonton, which is 2.5 hrs. from Calgary. Last fall I went to the berland river south of whitecourt and caught 4 or 5 dozen in an afternoon with a silver spinner.
Not fully sure on the sturgeon but the North Saskatchewan river is very good fishing in September. Big pike, pickeral, and rocky mountain whites in the fall. quite a few sturgeon in the river are caught by Gennesee bridge 40 miles upstream of edmonton or the east side of edmonton by strathcona science park.
Good luck and enjoy, which ever you choose.
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